Electrochemistry

05/30/2003


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Table of Contents

Electrochemistry

Applications of Electroanalysis

Applications of Electroanalysis

Applications of Electroanalytical Chemistry

Corrosion - Some Statistics

Corrosion - Some Statistics

Fundamental Terminology

Review of Fundamental Terminology

Useful Pneumonics

Rules for Assigning Oxidation States

Rules for Determining Oxidation States

Rules for Assigning Oxidation States

Rules for Assigning Oxidation States

Rules for Assigning Oxidation States

Rules for Assigning Oxidation States

Rules for Assigning Oxidation States

Problem

Oxidants and Reductants

Problem

Review of Fundamental Terminology

What Makes Electrochemistry Interesting?

Copper Plating

Boring! Well, what if we could separate the oxidant from the reductant?

1836 The Daniell Cell

The Daniell Cell

Terminology

Problem: True or False

The Potential Scale

SHE

Standard Reduction Potentials

Calculating the Cell Potential

Problem:

Line Notation, an Electrochemical Shorthand

Problem

Thermodynamic Significance of Potentials

Thermodynamic Significance of Potentials

Thermodynamic Significance of Potentials

Electrochemical Cells - 2 Types

Electrochemical Cells - 2 Types

Problem

Answer

Problem

Problem

Predicting the Spontaneity of Redox Reactions - The Diagonal Rule

Problem

Question

Standard State

How do Cell Potentials Change if We are Not at Standard State?

How do Cell Potentials Change if We are Not at Standard State?

Problem

Problem:

Author: Northeastern University

Email: p.mabrouk@neu.edu

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